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Atropisomerism in a thermally switchable, cyclometallated iridium complex

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journal contribution
posted on 22.10.2014, 11:17 by Ashlee J. Howarth, David L. Davies, Francesco Lelj, Michael O. Wolf, Brian O. Patrick
Two stable diastereomeric atropisomers of a cyclometallated iridium complex containing a pyrene functionalized pyridine imine ligand have been isolated. These are the first fully characterized examples of metal containing atropisomers in which the rotational axis is not between two chelating atoms. The atropisomers can be converted thermally via a rocking motion of the pyrene moiety.

History

Citation

Dalton Transactions, 2012, 41 (34), pp. 10150-10152

Author affiliation

/Organisation/COLLEGE OF SCIENCE AND ENGINEERING/Department of Chemistry

Version

AM (Accepted Manuscript)

Published in

Dalton Transactions

Publisher

Royal Society of Chemistry

issn

1477-9226

eissn

1477-9234

Copyright date

2012

Available date

22/10/2014

Publisher version

http://pubs.rsc.org/en/Content/ArticleLanding/2012/DT/c2dt31120h#!divAbstract

Language

en