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Triol protection with 6-benzoyl-3,4-dihydro-(2H)-pyran.

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posted on 08.12.2009, 16:23 by Caroline D. L. Baker, John Fawcett, Christopher D. Insley, Derek S. Messenger, Claire L. Newland, Helen L. Overend, Anup B. Patel, Mufakhrul Shah, Bhavna Vara, Davinder Virdee, Bernard J. Rawlings
6-Benzoyl-3,4-dihydro-(2H)-pyran will protect 1,2,3-triols such as glycerol as their corresponding spiro-[5-phenyl-3,6,8-trioxabicyclo[3.2.1]octane-4,2′-tetrahydropyran]s and 1,2,4-triols (less efficiently) as the corresponding trioxabicyclo[3.2.2]nonanes; the hexol mannitol is converted into the corresponding bis-protected product.
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Citation

Chemical Communications, 2005, pp.1883-1885

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VoR (Version of Record)

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Chemical Communications

Publisher

The Royal Society of Chemistry

issn

1359-7345

eissn

1364-548X

Copyright date

2005

Available date

08/12/2009

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http://pubs.rsc.org/en/Content/ArticleLanding/2005/CC/b418035f#!divAbstract

Language

en

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